Posted in | News | Quantum Dots

Researchers Improve the Manufacturing Process for Quantum Dots

Quantum dots could one day constitute the basic information units of quantum computers. In collaboration with colleagues from Copenhagen and Basel, researchers from Ruhr-Universität Bochum (RUB) and the Technical University of Munich (TUM) have decisively improved the manufacturing process for these tiny semiconductor structures.

The quantum dots are generated on a wafer: a thin semiconductor crystal disc. To date, the density of such structures on the wafer has been difficult to control. Now, researchers can create specific arrangements in a targeted manner – an important step towards an applicable component that would be expected to have a large number of quantum dots.

The team published its findings on 28 March 2022 in the journal Nature Communications. The study was conducted by a group headed by Nikolai Bart, Professor Andreas Wieck and Dr. Arne Ludwig from the RUB Chair of Applied Solid State Physics in cooperation with the team led by Christian Dangel and Professor Jonathan Finley from the TUM Semiconductor Nanostructures and Quantum Systems research group and colleagues from the Universities of Copenhagen and Basel.

Like M​​​​​ushrooms in the Forest

Quantum dots are narrowly defined areas in a semiconductor in which, for example, a single electron can be confined. This can be manipulated from the outside, for example with light, so that information can be stored in the quantum dot. The researchers from Bochum are experts in the production of quantum dots. They create the structures on a wafer made of a semiconductor material that is about the size of a beer coaster. The quantum dots have a diameter of only about 30 nanometres.

"Our quantum dots used to grow like mushrooms in the forest," as Andreas Wieck describes the initial situation. "We knew that they would emerge somewhere on the wafer, but not exactly where." The researchers then chose a suitable mushroom in the forest for their experiments with the quantum dots.

Preliminary Cultivation Experiments

In a number of preliminary experiments, the team had already tried to influence the growth of the quantum dots on the wafer. The physicists had irradiated the wafer at individual points with focused ions, thus creating defects in the semiconductor crystal lattice. Acting like condensation nuclei, these defects provoked the growth of quantum dots. "But just as cultivated mushrooms taste somewhat bland while forest mushrooms taste great, the quantum dots created in this way were not as high quality as the naturally grown quantum dots," illustrates Andreas Wieck. They did not radiate light as perfectly.

Therefore, the team proceeded with the naturally grown quantum dots. For the experiments, the beer coaster-sized wafer was cut into millimetre-small rectangles. They couldn't analyse the whole wafer at once, because the vacuum chamber of the RUB apparatus simply wasn't big enough. However, the researchers observed that some wafer rectangles contained many quantum dots, while others contained few. "At first, we didn't notice any system behind it," Andreas Wieck recalls – because the researchers never saw the whole picture.

High-quality Quantum Dots

To explore the question in depth, the Bochum team cooperated with their colleagues at the TUM, who had a measuring device with a larger sample chamber at their disposal at an early stage. During these analyses, the group found that there was a strange distribution of areas with high and low quantum dot densities on the wafer. "The structures were strongly reminiscent of a moiré pattern that often occurs in digital images. I soon hit on the idea that it must actually be a concentric pattern, i.e. rings, and that these could be seen in correlation to our crystal growth," explains Arne Ludwig. Measurements with higher resolution indeed showed that the density of quantum dots was distributed concentrically. Subsequently, the researchers confirmed that this arrangement was due to the manufacturing process.

In the first step, the wafer is coated with additional atomic layers. Due to the geometry of the coating system, this creates ring-shaped structures that have a complete atomic layer, i.e. where no atom is missing at any point in the layer. Between the rings, similarly wide areas are formed that lack a complete atomic layer and thus have a rougher surface because individual atoms are missing. This has consequences for the growth of the quantum dots. "To stick with the image: rather than on a concreted surface, mushrooms prefer to grow on forest floor, i.e. on the rough spots on the wafer," says Andreas Wieck.

The researchers optimised the coating process so that the rough areas appeared at regular intervals – of less than a millimetre – on the wafer and that the rings intersected. This resulted in an almost chessboard-like pattern with quantum dots of high quality, as demonstrated by the researchers from Basel and Copenhagen.


Tell Us What You Think

Do you have a review, update or anything you would like to add to this news story?

Leave your feedback
Your comment type